Search results for "pole [resonance]"
showing 10 items of 238 documents
Preparation and XAFS studies of organotin(IV) complexes with adenosine and related compounds and calf thymus DNA
2007
Complexes of adenosine and related compounds (adenosine-5’-monophosphate, adenosine-5’-triphosphate and pyridoxal-5-phosphate) with Bu2SnO and/or BuSnCl2 were prepared in the solid state. The compositions of the complexes were determined by standard analytical methods. It was found that the complexes contain the organotin(IV) moiety and the ligand in a ratio of 1:1. The FT-IR spectra demonstrated that Bu2SnO reacts with the D-ribose moiety of the ligands, while Bu2SnCl2 is coordinated to the deprotonated phosphate group. The basic part of the ligands does not participate directly in complex formation. Comparison of the experimental Mossbauer Δ (quadrupole splitting) values with those calcul…
Fano-resonances in High Index Dielectric Nanowires for Directional Scattering
2018
High refractive index dielectric nanostructures provide original optical properties thanks to the occurrence of size- and shape-dependent optical resonance modes. These modes commonly present a spectral overlap of broad, low-order modes (\textit{e.g}. dipolar modes) and much narrower, higher-order modes. The latter are usually characterized by a rapidly varying frequency-dependent phase, which - in superposition with the lower order mode of approximately constant phase - leads to typical spectral features known as Fano resonances. Interestingly, such Fano resonances occur in dielectric nanostructures of the simplest shapes. In spheroidal nanoparticles, interference between broad magnetic di…
Realization of Regional Operational Programme of the Opolskie Voivodeship 2014-2020. Assumption and Activities In the Opole Agglomeration in the Cont…
2019
Celem artykułu jest identyfikacja i ocena działań mających wpływ na rozwój aglomeracji opolskiej na gruncie koncepcji zrównoważonego rozwoju. Istotne jest zidentyfikowanie działań podejmowanych w zakresie prowadzonej polityki w ramach istniejącego obszaru funkcjonalnego oraz ich ocena w kontekście założeń zrównoważonego rozwoju. Aby zrealizować tak określony cel, analizę oparto na typach projektów finansowanych w ramach RPO WO 2014-2020 oraz zasięgu ich oddziaływania. W rozważaniach uwzględniono trzy główne aspekty rozwoju zrównoważonego: ekonomiczny, społeczny oraz środowiskowy. Ponadto starano się zidentyfikować korzyści płynące z prowadzonych przez Stowarzyszenie Aglomeracji Opolskiej dz…
Interactions of organotins with biological systems
1992
The bonding and structure in the environments of tin atoms in organotin-biological molecules has been investigated by 119Sn Mossbauer spectroscopy, mainly through the rationalization of the nuclear quadrupole splitting parameter by pointcharge model approaches. Organotin moieties R2SnIV and R3SnIV (R = Me, nBu, Ph) generally assume trigonal-bipyramidal type configurations in membranes of human erythrocytes, when incubated with whole erythrocytes and erythrocyte ghosts at the level of micromolar (μmol dm−3) organotin per mg of membrane protein. Corresponding structures are assumed by Me2SnIV and Me3SnIV in the cytoplasm. Ethanolic Me2SnCl2 yielded distorted trans-octahedral species when reac…
119Sn Mössbauer spectroscopic studies of the products of the reaction of triorganotin(IV) derivatives with 6-thiopurine
1985
Abstract A structural study of the products of the reaction of R 3 Sn IV derivatives (R = Me, Bu n , Ph) with 6-thiopurine, 6-TPH 2 , and its sodium salt, 6-TPHNa, has been undertaken using Mossbauer spectroscopy and the point-charge model rationalization of the Mossbauer parameter nuclear quadrupole splitting. The synthetic reactions have been carried out at ca . 0 °C, 20 °C and 50 °C. The Mossbauer spectra of the complexes AlK 3 Sn(6-TPH) are consistent with the occurrence of two distinct tin(IV) sites in samples prepared at the lower temperature, while one only site appears by increasing the temperature of the reaction. Two tin sites constantly occur in the products of the reactions invo…
Chemical Applications of Mössbauer Spectroscopy
2012
The Tutorial Lecture begins with a brief recapitulation of the hyperfine interactions and the relevant parameters observable in a Mossbauer spectrum. The main chapter with selected examples of chemical applications of Mossbauer spectroscopy follows and is subdivided into sections on: basic information on structure and bonding; switchable molecules (thermal spin transition in mono- and oligonuclear coordination compounds, light-induced spin transition, nuclear-decay-induced spin transition, spin transition in metallomesogens); mixed-valency in biferrocenes and other iron coordination compounds, and in an europium intermetallic compound; electron transfer in Prussian blue-analog complexes; mo…
Tin(IV), Monomethyltin(IV), and Dimethyltin(IV) Complexes with thiol sulfur and heterocyclic nitrogen donors: Molecular dynamics and structure by119S…
1995
The molecular dynamics of the complexes Sn(SPyN)4 (1), SnCl2(SPyN)2 (2), MeSn(SPy)3 (3), MeSnCl(SPyN)2 (4), Me2Sn(TCy)2 (5), Me2SnCl(TOx) (6), and Me2Sn(TUr) (7) [HSPy = 2-mercaptopyridine; HSPyN = 2-mercaptopyrimidine; HTCy = 2-thiocytosine; HTOx = 8-thioquinoline; H2TUr = 2-thiouracil] has been investigated by variable temperature 119Sn Mossbauer spectroscopy. The area under the resonant peaks has been determined as function of temperature, from which Debye temperatures and cut-off frequencies, as well as recoil-free fractions (Lamb Mossbauer factor) and mean square displacements of 119Sn, have been calculated. By fingerprint procedures on the basis of literature data, monomeric structure…
Compte rendu de : Owen White, The blood of the colony. Wine and the Rise and Fall of French Algeria, Cambridge Massachusetts, London, Harvard Univers…
2021
International audience
Monitoring Water and Energy Cycles at Climate Scale in the Third Pole Environment (CLIMATE-TPE)
2021
A better understanding of the water and energy cycles at climate scale in the Third Pole Environment is essential for assessing and understanding the causes of changes in the cryosphere and hydrosphere in relation to changes of plateau atmosphere in the Asian monsoon system and for predicting the possible changes in water resources in South and East Asia. This paper reports the following results: (1) A platform of in situ observation stations is briefly described for quantifying the interactions in hydrosphere-pedosphere-atmosphere-cryosphere-biosphere over the Tibetan Plateau. (2) A multiyear in situ L-Band microwave radiometry of land surface processes is used to develop a new microwave r…
Starzec wąskolistny Senecio inaequidens D.C. w pasie autostrady koło Brzegu na Śląsku Opolskim
2018
The paper presents the vegetation types with invasive Senecio inaequidens along the road verges in the Opole Silesia. The large population of this South-African species was located in the second half of June 2018 in the green belt (central reservation) along the A4 motorway (motorway section Brzeg – Opole).